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1995). Half a century of hard metals. Metal Powder Report, 22–28. Brookes, K. J. A. (1996). ). International Carbide Data. Campbell, J. , Powell, C. , Nowicky, D. , & Gonser, B. W. (1948). The vapour-phase deposition of refractory materials; I. General conditions and apparatus. Journal of the Electrochemical Society, 96, 318. Derjagin, B. , Spitsyn, B. , Builov, L. , Klochkov, A. , Gorodetskii, A. , & Smol’yaninov, A. V. (1976). Synthesis of diamond on non-diamond substrates. Doklady Akademii Nauk SSSR, 231, 333–335.

3 Aluminum Oxide Coatings The supreme hardness of aluminum oxide and its resistance against oxidative attack and diffusion processes has led to efforts to study the possibility to coat hardmetals with aluminum oxide. However, the adhesion of such layers on hardmetals is low. Hence, this must be counterbalanced by intermediate layers of TiC or Ti(C,N) as was demonstrated by respective developmental work at Batelle Geneve (Lux, Funk, Schachner, & Triquet, 1974). 4 Diamond Coatings There are only very few substances which are even harder than aluminum oxide.

Most interestingly, LSRH had developed a process of coating the steel cases of wristwatches with TiC in order to make them resistant against scratches in the early 1960s. This was considerably cheaper than to manufacture such cases from sintered hardmetals. Dr Richard Kieffer who had become professor at the Vienna University of Technology after being the managing director of Metallwerk Plansee had heard early about the successful attempts to produce coated hardmetals and also about the introduction of the latter to the hardmetal market.

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