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Extra resources for Coordination Polymerization. A Memorial to Karl Ziegler
Gatti, C. O. Crain, J r . D. Roberts, Macromole ouïes 49 U75 (1971). Y. Takegami, and T. Suzuki, Bull. Chem. Soo. Japan* 42, 8h8 (1969). A. Zambelli, C. Tosi, and C. Sacchi, MaoromoleoulesΛ 5, 6h9 ( 1 9 7 2 ) . Unpublished data from our laboratory. A. L. Segre, M. Farina, and G. Natta, Makromol. M 110, 1 (1967). 23 A. Z A M B E L L t (16) (17) F. HEATLEY, 2, 619 (1969). R. A. ZAMBELLI, S O L O V E Y , AND F . A . E. (19) A. ZAMBELLI, L. L. MALLOWS, AND F . A . (20) A. (21) A . Z A M B E L L I , AND C .
Unpublished data from our laboratory. A. L. Segre, M. Farina, and G. Natta, Makromol. M 110, 1 (1967). 23 A. Z A M B E L L t (16) (17) F. HEATLEY, 2, 619 (1969). R. A. ZAMBELLI, S O L O V E Y , AND F . A . E. (19) A. ZAMBELLI, L. L. MALLOWS, AND F . A . (20) A. (21) A . Z A M B E L L I , AND C . T O S I , Ado. IN P R E S S . E . J . ARLMAN AND P . C O S S E E , J . (22) AND C . 9 BOVEY, WOLFSGRUBER, BOVEY, 1565 ( I 9 6 0 ) . ZAMBELLI, A. A AND F . A . 59 hko (1972). L. RICHARD, Maoromolecules 69 925 (1973)· Macromoleaules, (18) DORMAN, A .
OF THE TWO P O S S I B L E EXPLANATIONS FOR THE ABOVE DIFFERENCE, I . E . A D I F F E R E N T NUMBER OF CATALYTIC CENTERS HAVING O P P O S I T E C H I R A L I T Y , OR A M O D I F I C A T I O N OF THE R E A C T I V I T Y OF THE TWO ENANTIOMERIC S I T E S TOWARDS THE TWO ANTIPODES OF THE MONOMER B Y INTRODUCING A NEW ASYMMETRIC CENTER HAVING A HOWPREDOMINANT C H I R A L I T Y , THE SECOND APPEARS MORE L I K E L Y . E V E R , THE NATURE OF THE MODIFICATION OF THE CATALYTIC CENTERS CREATED B Y CHIRAL CATALYST COMPONENTS I S S T I L L O B S C U R E , ALTHOUGH SOME ATTEMPTS HAVE B E E N MADE TO CORRELATE THE D I F FERENCE I N S T E R E O E L E C T I V I T Y OF CATALYTIC SYSTEMS PREPARED FROM ZINC ALKYLS AND ALUMINUM ALKYLS WITH THE P O S S I B L E M O D I F I C A T I O N OF THE CATALYTIC C E N T E R S .