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By Wright F. E.

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1) are indicated by the open circles. Values for ωmax were taken from [35, 47, 48].

Realization of solid-state laser cooling in the mid-1990s coincided with an intense effort in academia and industry to develop and commercialize ultra-low-loss fluoride glass fibers for long-haul fiber-optic telecommunications. The focus was on heavy metal fluoride glasses (HMFG), and ZBLAN (ZrF4 -BaF2 LaF3 -AlF3 -NaF) glass in particular. 5 µm). The field was fueled by the prospect of realizing transoceanic fluoride fiber-optic links without the need for signal amplification, which is not possible with silica fibers.

No net cooling was achieved, despite the realization of an impressive external quantum efficiency of 96% in GaAs. These experiments used a highquality GaAs heterostructure that was optically contacted with a ZnSe dome structure for enhanced luminescence extraction. A report of local cooling in AlGaAs quantum wells by a European consortium [53] was later attributed to misinterpretation of spectra caused by Coulomb screening of the excitons [80]. 8b displays anti-Stokes luminescence in a GaAs heterostructure, where excitation at λ = 890 nm produces broadband luminescence with a mean wavelength of λf W 860 nm.

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